Can customers use S2SVPN and VNET Peering to connect to PCE at the same time?

As the subject,

As I know, According to R&R Matrix "INFRA_1.2.0.5_PCE" the RISE lawsuit is entitled to 1 Azure VNET Peering and further connections tin beryllium purchased. 

Does Customer usage 1 Azure VNET Peering and S2SVPN astatine the aforesaid time?